Search results for " corrosion"
showing 10 items of 152 documents
Influence of Centerline Intermetallic Stringers on Pitting Corrosion Resistance of Superduplex Stainless Steel
2021
Superduplex stainless steel UNS S32750 / EN 1.4410 is commonly used in marine environment, petrochemical, oil and gas, chemical and desalination industries, requiring materials with superior corrosion and mechanical properties. Very few residual intermetallic particles may be present under the form of centerline stringers whose effects on corrosion properties are not well documented. A previous study demonstrated the negligible influence of the intermetallic phases in centerline stringers (typically < 0.1% over thickness) on the hydrogen embrittlement susceptibility of superduplex stainless steel [1]. The present study aims at highlighting the impact of centerline intermetallic stringers on…
Influence of mass transport on the competition between corrosion of aluminium alloy surface and the release of primer containing inhibitors : validat…
2014
The conventional aircraft paint scheme for corrosion protection of aluminum structures is partly based on application of a primer containing inhibitors. In such coatings, release of the inhibiting species enables fast healing of a bare metal surface after a mechanical damage of the protective layers. Nevertheless, considering possible depletion of inhibitors by uncontrolled leaching, it appears important to estimate the corrosion risk integrating “corrosion” sensors in the structure. The objective of this work was to understand the operating mode of a sensor simulating a damaged paint coating whose concept is based on the competition between the triggering of localized corrosion and the pas…
Conversion electron Mössbauer study of low carbon steel polarized in aqueous sulfate and sulfite containing sulfate solutions
1993
Abstract The passivation of low carbon steel was studied in aqueous solutions of 0.5 M Na 2 SO 4 (pH = 3.5 and 6.5) and of 0.5 M Na 2 SO 4 + 0.001 M NaHSO 3 (pH 3.5 and 6.5). The used conversion electron Mossbauer spectroscopy (CEMS) with the complementary electrochemical, microscopic and spectrophotometric investigations proved that the presence of sulfite ion induces pitting corrosion. The compositions and thichnesses of the passive films formed during the electrochemical treatments are determined from the conversion electron Mossbauer spectra. γ-FeOOH was found in each case as a major component. At pH = 3.5, the sextet belonging to Fe 3 C appears in the spectra in most cases, and also Fe…
Recovering bronze metallurgy from archaeological artefacts for the production of reference materials in conservation science
2007
The production of reference Cu-based alloys is the first step of an original experimental protocol to be used in the field of conservation and restoration of metal artefacts. The production of these synthetic alloys has a double value. They can be used both as suitable substitutes of unique archaeological pieces for testing new materials and methods for conservation, and as guidelines for contemporary metal production. We report on a research activity focused on the recovery of the ancient production techniques from the investigation of archaeological copper-based artefacts. The chemical, physical and metallurgical characterization of several Cu-based artefacts, found in different Italian a…
SVET, AFM and AES study of pitting corrosion initiated on MnS inclusions by microinjection
2003
As pitting is a random phenomenon, it is difficult to predict where a pit will appear on the surface and consequently the use of local probes is rendered difficult. In this work, a new method to study pitting corrosion on a MnS inclusion on 316L stainless steel is proposed. It consists in modifying locally the chemistry in its vicinity by injecting with a microcapillary an aggressive solution of NaCl, H2SO4 or HCl. Once a pit appears, scanning vibrating electrode technique (SVET) is used to follow the current fluctuations over and around the pit when the metal is polarized at a passive potential. In another series of experiments the effect of local activation of MnS inclusion was studied ex…
Influence of the grain orientation spread on the pitting corrosion resistance of duplex stainless steels using electron backscatter diffraction and c…
2013
Abstract The corrosion behavior of UNS S32202 duplex stainless steel was studied by combining electron backscatter diffraction (EBSD) measurements and critical pitting temperature tests at the microscale. The grain orientation spread (GOS) value was determined in grains of both phases from EBSD data. It was shown that austenitic sites containing extremely small ferrite grains having a GOS value greater than 1.3° were precursor sites for pitting in 4 M NaCl. The critical pitting temperature range was 45–90 °C. All the other sites of both phases remained passive up to 100 °C.
Localized hydrogen cracking in the austenitic phase of a duplex stainless steel
1996
The aim of this study is to investigate the role of hydrogen on the mechanical behavior of an austenitic phase, in the particular situation of duplex stainless steels. In these duplex alloys, in presence of hydrogen, the ferritic phase is embrittled by hydrogen and the resistance to cracking is mainly related to the behavior of the austenitic phase. Thus, a discussion of the role of hydrogen at the crack tip of a duplex alloy (as function of the microstructure) has been proposed by T. Perng and C.J. Altester after experiments conducted in gaseous environment. A similar experimental approach has been followed in this study; slow strain rate tests (SSRT) have been performed on duplex stainles…
Study of the mechanical effects on passivity breakdown by local probe techniques
2006
This paper aims at demonstrating that a relationship exists between surface stress and pitting corrosion. The surface stress field generated by polishing was first calculated using a thermo-mechanical model and a finite element code. Pitting corrosion tests performed at the microscale along the austenite/ferrite interface using the electrochemical microcell technique were then analyzed considering the microstructure and the residual surface stress field. Mechano-chemical criteria are proposed leading to an enhancement of pitting corrosion of duplex steels.
Influence of bond deterioration on shear-flexure failure of prestressed girders with post-tensioned tendons
2021
Internal prestressing with bonded tendons suffers corrosion of wires and bond deterioration due to the bad infill of grouted sheaths. Many bridge girders show this state through cracking, deflections and in the worst cases, sudden failures. In Italy these are common situations, and the internal tendon corrosion is among the major causes of bridge degradation and damage, especially for grouted post-tensioned tendons. This paper presents the analysis of failure of prestressed cross-sections considering shear and flexure in the case of bond deterioration due to corrosion of internal post-tensioned tendons. The structural behaviour is analysed for different typologies of bridge deck composed of…
Case-studies of corroded reinforced concrete bridges in Southern Italy
2020
On Italian roads, a lot of reinforced concrete bridges were built in the 1950’s and 1960’s for short spans, before the advent of prefabricated structures. Many of these bridges, sited on principal or secondary roadways, show the effects of corrosion of reinforcements and high levels of damage, leading to the likelihood of achievement of the Ultimate Limit State, below the required performances of serviceability, especially in the case of Gerber saddles having strongly corroded reinforcements. Different case studies of bridges sited in Southern Italy (Sicily) are shown, allowing engineers to classify the main effects of damage in corroded structures with the Gerber static scheme (cantilever …